The research using matching survey method from more than 300 high-tech enterprises showed that organizational emotional capability (OEC) has a positive impact on product, process innovation performance by mediation of organizational learning (OL). And organizational commitment plays a moderating role on the above path, so as to form a moderated mediation model. It is a meaningful research to explore the innovation mechanism and path from a new perspective of emotional capacity, which would help provide beneficial reference for innovation management practices in high-tech enterprises.