Along with the conversion of policy goals, the increase of policy makers main body, and the expansion of adjustment range for China's technology transfer policy system, the focus of policy making should turned to perfect policy system and establish operation mechanism. However, the present operation model of technology transfer policy still follows the conventional model which lays stress on single policy efficiency. The conflict between variety policies cancels out the efficacy of policy and there is a consequent internal friction in the policy system. The synergetic operation model of policies is an efficient operation model, which applies the fundamental principles of synergetics to the construction and operation of policy system. On the basis of this model, the proposition to establish synergetic operation mechanism for China's technology transfer policy system is put forward.