Abstract: Why only few people have the driving motivation for innovative entrepreneurship in reality? Based on the perspective of entrepreneurial opportunities, it attempts to examine the influence of risk attitude, human capital, and social network capital on innovative entrepreneurial career choice from the Panel Study of Entrepreneurial Dynamics II(PSED II) data by using the OLS model and logistic model. The acknowledgements of innovative entrepreneurship are enriched. The findings are also a great help to make the laws for promoting the innovative new venture creation.