Abstract: CEO’s leadership, mainly at the personal-level factor, affects the organizational performance through the factors of organizational level. By the method of empirical research, the relationship was analyzed among the leadership behavior, organizational learning capability, and organizational performance. The conclusions could be drawn as followed:（1）The three kinds of leadership behavior ofTRC model have significant effect on the organizational learning capability, in which the most importantis change-oriented, the second is relation-oriented, and the third is task-oriented according to the significant. (2) Organizationallearning capability has a complete mediate effect on the relationship between relation-oriented, change-oriented leadership behavior and organizational performance. Finally, the contribution, deficiency, and future development of the research are discussed.